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Standard enthalpy of formation, Gibbs energy of formation, entropy and molar heat capacity of organic substances

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ΔH°f : The standard enthalpy of formation at 25°C (298,15 K) for 1 mol of the substance in its given state (g= gas and l= liquide) from its elements in their standard state (stable forms at 1 bar and 25°C)

ΔG°f : The standard Gibbs free energy of formation at 25°C (298,15 K) for 1 mol of the substance in its given state (g= gas and l= liquide) from its elements in their standard state (stable forms at 1 bar and 25°C)

S°: The standard entropy for 1 mol of the substance in its given state (g= gas and l= liquide) at 1 bar and 25°C

Cp : The standard molar specific heat capacity of the substance in its given state (g= gas and l= liquide) at constant pressure and 25°C

See also Thermodyamics key values internationally agreed , and Standard state and enthalpy of formation, Gibbs free energy of formation, entropy and heat capacity for ΔH°f, ΔG°f, S° and Cp for more than 370 inorganic substances and gases , common liquids and fluids , food and foodstuff , metals and semimetals , common solids and other common substances for tabulated values of specific heat capacity, cp .

Standard enthalpy of formation, Gibbs energy of formation, entropy and molar heat capacity of organic substances
Substance Brutto formula ΔH°f @25°C
kJ/mol
ΔG°f @25°C
kJ/mol
S° @25°C
J/(mol K)
Cp @25°C
J/(mol K)
Bromoform (g) CHBr3 25 16 331 71
Chloroform (l) CHCl3 -134.1 -73.7 201.7 114.2
Chloroform (g) CHCl3 -102.7 6.0 295.7 65.7
Formic acid (l) CH2O 2 -425 -361.4 129 99
Formic acid (g) CH2O 2 -378.7
Methyl (g) CH3 145.7 47.9 194.2 38.7
Bromomethane (l) CH3 Br -59.8
Bromomethane (g) CH3 Br -35.4 -26.3 246.4 42.4
Chloromethane (g) CH3 Cl -81.9 -63 234.6 40.8
Fluormethane (g) CH3 F -234 -210 222.9 37.5
Iodomethane (l) CH3 I -13.6 136.2 126
Iodomethane (g) CH3 I 14.4 16 254.1 44.1
Nitromethane (l) CH3 NO 2 -112.6 -14.4 171.8 106.6
Nitromethane (g) CH3 NO2 -80.8 -7 282.9 55.5
Methane (g) CH 4 -74.6 -50.5 186.3 35.7
Methanol (l) CH 4 O -239.2 -166.6 126.8 81.1
Methanol (g) CH 4 O -201 -162.3 239.9 44.1
Methylamine (l) CH5 N -47.3 35.7 150.2 102.1
Methylamine (g) CH5 N -22.5 32.7 242.9 50.1
Ethyne (acetylene) (g) C2H 2 226.9 209 201 44
Ethene (g) C2H 4 52.5 68.4 219.3 42.9
Acetic acid (l) C2H4O 2 -484.3 -389.9 159.8 123.3
Acetic acid (g) C2H4O 2 -432.2 -374.2 283.5 63.4
Bromoethane (l) C2H5 Br -90.5 -25.8 198.7 100.8
Bromoethane (g) C2H5 Br -61.9 -23.9 286.7 64.5
Chloroethane (l) C2H5 Cl -136.8 -59.3 190.8 104.3
Chloroethane (g) C2H5 Cl -112.1 -60.4 276 62.8
Nitroethane (l) C2H5 NO 2 -143.9 134.4
Nitroethane (g) C2H5 NO 2 -103.8 -5 320.5 79
Ethane (g) C2H6 -84 -32 229.2 52.5
Ethanol (l) C2H6 O -277.6 -174.8 160.7 112.3
Ethanol (g) C2H6 O -234.8 -167.9 281.6 65.6
Methoxymethane (l) C2H6 O -203,3
Methoxymethane (g) C2H6 O -184.1 -112.6 266.4
Ethylamine (l) C2H 7 N -74.1 130
Ethylamine (g) C2H 7 N -47.5 36.3 283.8 71.5
Cyclopropene (g) C3 H 4 277.1 286 244 53
Propyne (g) C3 H 4 185 194 248 61
Cyclopropane (l) C3 H6 35.2
Cyclopropane (g) C3 H6 53.3 104.5 237.5 55.6
Propene (g) C3 H6 20 62 267 64
Acetone (l) C3 H6 O -248.4 199.8 126.3
Acetone (g) C3 H6 O -217.1 -152.7 295.3 74.5
Propanoic acid (l) C3 H6 O 2 -510.7 191 152.8
Propanoic acid (g) C3 H6 O 2 -455.7
Propane (l) C3 H 8 -120.9
Propane (g) C3 H 8 -103.8 -23.4 270.3 73.6
1-Propanol (l) C3 H 8 O -302.6 193.6 143.9
1-Propanol (g) C3 H 8 O -255.1 322.6 85.6
2-Propanol (l) C3 H 8 O -318.1 181.1 156.5
2-Propanol (g) C3 H 8 O -272.6 309.2 89.3
1-Propanamine (g) C3 H 9 N -72 40 324
1-Butyne (l) C 4 H6 141.4
1-Butyne (g) C 4 H6 165.2 202 291 81
2-Butyne (l) C 4 H6 119.1
2-Butyne (g) C 4 H6 145.7 185 283 78
Cyclobutene (g) C 4 H6 156.7 175 64 64
2-Methyl-1-propene (g) C 4 H 8 -17 58 294 89
1-Butene (l) C 4 H 8 -20.8 227 118
1-Butene (g) C 4 H 8 0.1 71 306 86
Cyclobutane (l) C 4 H 8 3.7
Cyclobutane (g) C 4 H 8 27.7 110 265 nd
Butanoic acid (l) C 4 H 8 O 2 -533.8 222.2 178.6
Butanoic acid (g) C 4 H 8 O 2 -475.9
2-Methylpropane (g) C 4 H 10 -135 -21 295 97
Butane (l) C 4 H 10 -147.3 140.9
Butane (g) C 4 H 10 -125.7 -17 310 98
1-Butanol (l) C 4 H 10 O -327.3 225.8 177.2
1-Butanol (g) C 4 H 10 O -274.9
2-Butanol (l) C 4 H 10 O -342.6 214.9 196.9
2-Butanol (g) C 4 H 10 O -292.8 359.5 112.7
1-Pentyne (g) C5 H 8 144 210 330 105
2-Pentyne (g) C5 H 8 129 194 332 99
Cyclopentene (l) C5 H 8 4.3 201.2 122.4
Cyclopentene (g) C5 H 8 34 111 290 75
1-Pentene (l) C5 H 10 -46.9 262.6 154
1-Pentene (g) C5 H 10 -21.1 79 346 110
2-Methyl-1-butene (g) C5 H 10 -35.2 66 340 112
2-Methyl-1-butene (l) C5 H 10 -61.1 254 157.2
Cyclopentane (l) C5 H 10 -105.1 204.5 128.8
Cyclopentane (g) C5 H 10 -76.4 39 293 83
Pentanoic acid (l) C5 H 10 O 2 -559.4 259.8 210.3
Pentanoic acid (g) C5 H 10 O 2 -491.9
2,2-Dimethylpropane (g) C5 H 12 -166 -15 306 122
2-Methylbutane (g) C5 H 12 -155 -15 344 119
Pentane (l) C5 H 12 -173.5 167.2
Pentane (g) C5 H 12 -146.9 -8 349 120
1-Pentanol (l) C5 H 12 O -351.6 208.1
1-Pentanol (g) C5 H 12 O -294.6
2-Pentanol (l) C5 H 12 O -365.2
2-Pentanol (g) C5 H 12 O -311
3-Pentanol (l) C5 H 12 O -368.9 239.7
3-Pentanol (g) C5 H 12 O -314.9
Methyl tert-butyl ether(l) C5 H 12 O -313.6 265.3 187.5
Methyl tert-butyl ether(g) C5 H 12 O -283.7
Benzene (l) C6H6 49.1 124.5 173.4 136
Benzene (g) C6H6 82.9 129.7 269.2 82.4
Aniline (l) C6H7N 191.9
Aniline (g) C6H7N 87.5 -7 317.9 107.9
1-Hexyne (g) C6H10 124 219 369 128
Cyclohexene (l) C6H10 -28.5 214.6 148.3
Cyclohexene (g) C6H10 -5 107 311 105
1-Hexene (l) C6H12 -74.2 295.2 183.3
1-Hexene (g) C6H12 -43.5 87 385 132
2-Methyl-1-pentene (g) C6H12 -59.4
2-Methyl-1-pentene (l) C6H12 -90
Cyclohexane (l) C6H12 -156.4 154.9
Cyclohexane (g) C6H12 -123.4 32 298 106
Methylcyclopentane(g) C6H12 -106.2
Methylcyclopentane(l) C6H12 -137.9
Hexanoic acid (l) C6H12O2 -583.8
Hexanoic acid (g) C6H12O2 -511.9
2,2-Dimethylbutane(g) C6H14 -185.9 -10 358 142
2,2-Dimethylbutane(l) C6H14 -213.8 272.5 191.9
2-Methylpentane (g) C6H14 -174.6 -5 381 144
2-Methylpentane (l) C6H14 -204.6 290.6 193.7
3-Methylpentane (g) C6H14 -171.9 -2 380 143
3-Methylpentane (l) C6H14 -202.4 292.5 190.7
Hexane (l) C6H14 -198.7 195.6
Hexane (g) C6H14 -166.9 -0.3 388 143
1-Hexanol (l) C6H14O -377.5 287.4 240.4
1-Hexanol (g) C6H14O 315.9
2-Hexanol (l) C6H14O -392
2-Hexanol (g) C6H14O -333.5
Phenol (s) C7H6O -165.1 144 127.4
Phenol (g) C7H6O -96.4 -33 316 104
Methylbenzene(l) C7H8 12.0 220 156
Methylbenzene(g) C7H8 50.0 122 321 104
1-Heptene (l) C7H14 -97.9 327.6 211.8
1-Heptene (g) C7H14 -62.3 96 424 15
Cycloheptane (l) C7H14 -156.6
Cycloheptane (g) C7H14 -118.1
Ethylcyclopentane (l) C7H14 -163.4 279.9
Ethylcyclopentane (g) C7H14 -126.9
Methylcyclohexane(g) C7H14 -154.7
Methylcyclohexane(l) C7H14 -190.1 184.8
Heptanoic acid (l) C7H14O2 -610.2 265.4
Heptanoic acid (g) C7H14O2 -536.2
2,2-Dimethylpentane (g) C7H16 -205.7
2,2-Dimethylpentane (l) C7H16 -238.3 300.3 221.1
2-Methylhexane (g) C7H16 -194.5
2-Methylhexane (l) C7H16 -229.5 323.3 222.9
3-Methylhexane (g) C7H16 -191.3
3-Methylhexane (l) C7H16 -226.4
Heptane (l) C7H16 -224.2 224.7
Heptane (g) C7H16 -187.6 8 428 166
1-Heptanol (l) C7H16O -403.3 272.1
1-Heptanol (g) C7H16O -336.5
Ethylbenzene (l) C8H10 -12.3 183.2
Ethylbenzene (g) C8H10 29.9 131 361 128
1-Octene (l) C8H16 -124.5 241
1-Octene (g) C8H16 -81.3 104 463 178
Cyclooctane (l) C8H16 -167.7
Cyclooctane (g) C8H16 -124.4
Ethylcyclohexane (l) C8H16 -212.1 280.9 211.8
Ethylcyclohexane (g) C8H16 -171.5
Octanoic acid (l) C8H16O2 -636 297.9
Octanoic acid (g) C8H16O2 -554.3
2-Methylheptane (g) C8H18 -215.3
2-Methylheptane (l) C8H18 -255 356.4 252
3-Methylheptane (g) C8H18 -212.5
3-Methylheptane(l) C8H18 -252.3 362.6 250.2
Octane (l) C8H18 -250.1 254.6
Octane (g) C8H18 -208.5 16 467 189
1-Octanol (l) C8H18O -426.5 305.2
1-Octanol (g) C8H18O -355.6
2,2-Dimethylhexane (g) C8H19 -224.5
2,2-Dimethylhexane (l) C8H19 -261.9
Propylcyclohexane (g) C9H1 -192 420 242
Propylbenzene (g) C9H12 8 137 401 154
1-Nonyne (l) C9H16 16.3
1-Nonyne (g) C9H16 62.3
Nonanoic acid (l) C9H18O2 -659.7 362.4
Nonanoic acid (g) C9H18O2 -577.3
2,2-Dimethylheptane(g) C 9 H 20 -246
2,2-Dimethylheptane(l) C 9 H 20 -288.1
Nonane (l) C 9 H 20 -274.7 284.4
Nonane (g) C 9 H 20 -228.2 25 506 212
1-Nonanol (l) C 9 H 20 O -453.4
1-Nonanol (g) C 9 H 20 O -376.5
Naphthalene (g) C 10 H 8 151 224 336
Butylbenzene (l) C 10 H 14 -63.2 321.2 243.4
Butylbenzene (g) C 10 H 14 -11.8
1-Decene (l) C 10 H 20 -173.8 425 300.8
1-Decene (g) C 10 H 20 -123.3 301
Butylcyclohexane (l) C 10 H 20 -263.1 345 271
Butylcyclohexane (g) C 10 H 20 -213.7
Decanoic acid (s) C 10 H 20 O 2 -713.7
Decanoic acid (l) C 10 H 20 O 2 -684.3
Decanoic acid (g) C 10 H 20 O 2 -594.9
2-Methylnonane (g) C 10 H 22 -260.2
2-Methylnonane (l) C 10 H 22 -309.8 420.1 313.3
Decane (l) C 10 H 22 -300.9 314.4
Decane (g) C 10 H 22 -249.5 33 545 235
1-Decanol (l) C 10 H 22 O -478.1 370.6
1-Decanol (g) C 10 H 22 O -396.6
1-Methylnaphthalene (l) C 11 H 10 56.3 254.8 224.4
2-Methylnaphthalene (s) C 11 H 10 44.9 220 196
2-Methylnaphthalene (g) C 11 H 10 106.7
1-Undecene (g) C 11 H 22 344.9
Undecane (l) C 11 H 24 -327.2 344.9
Undecane (g) C 11 H 24 -270.8 42 584 257
1-Undecanol (l) C 11 H 24 O -504.8
1-Dodecene (l) C 12 H 24 -226.2 484.8 360.7
1-Dodecene (g) C 12 H 24 -165.4
Dodecanoic acid (s) C 12 H 24 O 2 -774.6 404.3
Dodecanoic acid (l) C 12 H 24 O 2 -737.9
Dodecanoic acid (g) C 12 H 24 O 2 642
Dodecane (l) C 12 H 26 -350.9 375.8
Dodecane (g) C 12 H 26 -289.4 50 623 280
1-Dodecanol (l) C 12 H 26 O -528.5 438.1
1-Dodecanol (g) C 12 H 26 O -436.6
Anthracene (g) C 14 H 10 231
Phenantrene (g) C 14 H 10 207
Decylcyclopentane (l) C 15 H 30 -367.3
Decylbenzene (l) C 16 H 26 -218.3
Decylbenzene (g) C 16 H 26 -138.6
1-Hexadecene (l) C 16 H 32 -328.7 587.9 488.9
1-Hexadecene (g) C 16 H 32 -248.4
Hexadecanoic acid (s) C 16 H 32 O 2 -891.5 452.4 460.7
Hexadecanoic acid (l) C 16 H 32 O 2 -838.1
Hexadecanoic acid (g) C 16 H 32 O 2 -737.1
N-hexadecane (l) C 16 H 34 -456.1 501.6
N-hexadecane (g) C 16 H 34 -374.8
Chrysene (s) C 18 H 12 145.3
Chrysene (g) C 18 H 12 269.8
.

See also Standard state and enthalpy of formation, Gibbs free energy of formation, entropy and heat capacity for ΔH°f, ΔG°f, S° and Cp for more than 370 inorganic substances and gases , common liquids and fluids , food and foodstuff , metals and semimetals , common solids and other common substances for tabulated values of specific heat capacity, cp .

For conversion of units, use the Specific heat online unit converter.

The specific heat capacity can be calculated from the molar heat capacity, and vise versa:

cp = Cp / M    and

Cp = cp . M

where

cp = specific heat capacity

Cp = molar heat capacity

M = molar weight of the actual substance (g/mol).


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