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According to Newton's Law of Cooling heat transfer rate is related to the instantaneous temperature difference between hot and cold media
The the mean temperature difference in a heat transfer process depends on the direction of fluid flows involved in the process. The primary and secondary fluid in an heat exchanger process may

With saturation steam as the primary fluid the primary temperature can be taken as a constant since the heat is transferred as a result of a change of phase only. The temperature profile in the primary fluid is not dependent on the direction of flow.
The rise in secondary temperature is non-linear and can best be represented by a logarithmic calculation. A logarithmic mean temperature difference is termed
LMTD can be expressed like
LMTD = (Δto - Δti) / ln(Δto / Δti) (1)
where
LMTD = Logarithmic Mean Temperature Difference (oF, oC)
Δti = tpi - tsi = inlet primary and secondary fluid temperature difference (oF, oC)
Δto = tpo - tso = outlet primary and secondary fluid temperature difference (oF, oC)
The Logarithmic Mean Temperature Difference is always less than the Arithmetic Mean Temperature Difference.
An easier but less accurate way to calculate the mean temperature difference is the
AMTD can be expressed as:
AMTD = (tpi + tpo) / 2 - (tsi + tso) / 2 (2)
where
AMTD = Arithmetic Mean Temperature Difference (oF, oC)
tpi = primary inlet temperature (oF, oC)
tpo = primary outlet temperature (oF, oC)
tsi = secondary inlet temperature (oF, oC)
tso = secondary outlet temperature (oF, oC)
A linear increase in the secondary fluid temperature makes it more easy to do manual calculations. AMTD will in general give a satisfactory approximation for the mean temperature difference when the smallest of the inlet or outlet temperature differences is more than half the greatest of the inlet or outlet temperature differences.
When heat is transferred as a result of a change of phase like condensation or evaporation the temperature of the primary or secondary fluid remains constant. The equations can then be simplified by setting
tp1 = tp2 or ts1 = ts2 (oF, oC)
The calculator below can be used to calculate Arithmetic and Logarithmic Mean Temperature Difference of counter-flow an parallel-flow heat exchangers.
Hot water at 80oC heats air from from a temperature of 0oC to 20oC in a parallel flow heat exchanger. The water leaves the heat exchanger at 60oC.
Arithmetic Mean Temperature Difference can be calculated like
AMTD = (80oC + 60oC) / 2 - (0oC + 20oC) / 2
= 60 oC
Logarithmic Mean Temperature Difference can be calculated like
LMTD = (60oC - 20oC) - (80oC - 0oC)) / ln((60oC - 20oC) / (80oC - 0oC))
= 57,7 oC
Steam at 2 bar gauge heats water from 20oC to 50oC. The saturation temperature of steam at 2 bar gauge is 134oC.
Note! that team will condensate at a constant temperature. The temperature on the heat exchangers surface on the steam side is constant and determined by the steam pressure.
Arithmetic Mean Temperature Difference can be calculated like
AMTD = (134oC + 134oC) / 2 - (20oC + 50oC) / 2
= 99 oC
Log Mean Temperature Difference can be calculated like
LMTD = (134oC - 20oC - (134oC - 50oC)) / ln((134oC - 20oC) / (134oC - 50oC))
= 98.24 oC
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