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The second law of thermodynamics requires that the adiabatic and frictionless flow of any fluid results in no change in entropy. Constant entropy flow is called isentropic flow.
Based on the equation of entropy in a compressible flow:
ds = cv ln(T2 / T1) + R ln(ρ1 / ρ2) = cp ln(T2 / T1) - R ln(p2 / p1) = 0 (1)
where
ds = entropy change
cv = specific heat capacity at a constant volume process
cp = specific heat capacity at a constant pressure process
ρ = density of gas
Using
κ = cp / cv (2)
where
(1) can be transformed to:
(T2 / T1)(κ/(κ-1)) = (ρ2 / ρ1)κ = (p2 / p1) (3)
(3) express the useful relationship between temperature, density and pressure for an isentropic flow of an ideal gas.
From (3) the relationship between pressure and temperature can be concluded:
p / ρκ = constant (4)
Density can be expressed:
ρ = 1 / v (5)
where
v = specific volume
Using (5) in combination with (4) transforms to a common expression:
p vκ = constant (6)
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