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pH Definition

An introduction to pH

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pH can be viewed as an abbreviation for power of Hydrogen - or more completely, power of the concentration of the Hydrogen ion.

The mathematical definition of pH is a bit less intuitive but in general more useful. It says that the pH is equal to to the negative logarithmic value of the Hydrogen ion (H+) concentration, or

pH = -log [H+]

pH can alternatively be defined mathematically as the negative logarithmic value of the Hydroxonium ion (H3O+) concentration. Using the Bronsted-Lowry approach

pH = -log [H3O+]

pH values are calculated in powers of 10. The hydrogen ion concentration of a solution with pH 1.0 is 10 times larger than the hydrogen concentration in a solution with pH 2.0. The larger the hydrogen ion concentration, the smaller the pH.

  • when the pH is above 7 the solution is basic (alkaline)
  • when the pH is below 7 the solution is acidic

In pure neutral water the concentration of hydrogen and hydroxide ions are both 10-7 equivalents per liter.

pH Ion Concentration (gram equivalent per liter) Type of Solution
0 1.0 Acid Solution
- Hydrogen ions -
H+
1 0.1
2 0.01
3 0.001
4 0.0001
5 0.00001
6 0.000001
7 0.0000001 Neutral Solution
8 0.000001 Basic (alkaline) Solution
- Hydroxide ions -
OH-
9 0.00001
10 0.0001
11 0.001
12 0.01
13 0.1
14 1.0

Some common Products and their pH Values

pH values in some common products:

Product pH
Battery Acid 0
HCl in stomach acid 1
Lemon juice, vinegar 2-3
Orange juice 3-4
Acid rain 4
Black coffee 5
Urine, salvia 6
Pure water 7
Sea water 8
Baking soda 9
Ammonia solution 10-11
Soapy water 12
Bleach 13
Oven cleaner 13-14
Drain cleaner 14

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