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Diffusion Coefficients

A substance will flow from a region of high concentration to a region of low concentration

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Fick's first law states that substances flows from regions with higher concentrations to regions of lower concentrations. Fick's law can be expressed as

J = -D dφ/dx         (1)

where

J = diffusion flux - the amount of substance that flows through an unit area per unit time (mass or mol /m2s)

D = diffusion coefficient (m2/s)

dφ = concentration of substance (mass or mol / m3)

dx = length (m)

Diffusion Coefficients for some common Gases

Substance Diffusion Coefficient
- D -
(m2/s)
Water vapor, 0oC 22
Methane, 1 bar 20
Ethane 11
Air 19

 

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